It depends on how you send your 1:1 emails in ActiveCampaign. There are two ways:
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From your ActiveCampaign account
(Available on all plans)
No. If you send a 1:1 email from your ActiveCampaign account, it will NOT appear in your "Sent" folder. This is because these emails are sent using ActiveCampaign's servers. -
From an email account connected to ActiveCampaign
(Available on Sales Plus, Professional, and Enterprise)
Yes. If you send a 1:1 email from a connected email (Sales Plus, Professional, and Enterprise), it will appear in your connected email's "Sent" folder. This is because these emails are sent using the connected email's server.
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From your ActiveCampaign account
Note that, based on your plan, 1:1 emails can be sent from the Contacts Overview page, a Contact Record, a Deal record, an Account record, or an Automation.